Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/41164| Title: | Kinetics and mechanism of oxidation of aliphatic acetals with lead (IV) acetate |
| Authors: | Ahamed, K A Basheer Nambi, K |
| Issue Date: | Dec-1994 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The oxidative cleavage of aliphatic acetals of normal aliphatic aldehydes and substituted aliphatic aldehydes with aliphatic as well as aromatic alcohols with lead tetra acetate in acetic acid, aqueous acetic acid and in acetic acid-benzene medium is first order each in [oxidant] and [acetal] and yields the corresponding esters as the main product The rate of oxidation depends upon the dielectric constant of the medium, Stoichiometric investigations with different acetals indicated a 1:1 stoichiometry. |
| Page(s): | 1104-1109 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.33A(12) [December 1994] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 33A(12) 1104-1106.pdf | 631.82 kB | Adobe PDF | View/Open |
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