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http://nopr.niscpr.res.in/handle/123456789/41203Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Srinivasan, Bikshandarkoil R | - |
| dc.contributor.author | Dhavskar, Kiran T | - |
| dc.date.accessioned | 2017-04-11T10:51:36Z | - |
| dc.date.available | 2017-04-11T10:51:36Z | - |
| dc.date.issued | 2017-04 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://nopr.niscair.res.in/handle/123456789/41203 | - |
| dc.description | 387-393 | en_US |
| dc.description.abstract | The syntheses and crystal structure of the calcium coordination polymers [Ca(NMF)2(4-nba)2] 1 (4-nba = 4-nitrobenzoate; NMF=N-methylformamide) and [Ca(BA)2(4-nba)2] 2 (BA= benzamide) is reported. A unique μ2-η1: η1 bridging bidentate 4-nba ligand links the hexacoordinated Ca(II) ions situated on a special position in both compounds into a one-dimensional (1-D) chain with Ca···Ca separations of 5.561 and 5.482 respectively. Each Ca(II) in the chain is bonded to a pair of symmetry related terminal amide ligands (NMF in 1; BA in 2) which are disposed trans to each other. A comparative study of several 4-nitrobenzoates of calcium is described. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights | CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.56A(04) [April 2017] | en_US |
| dc.subject | Coordination chemistry | en_US |
| dc.subject | Coordination polymers | en_US |
| dc.subject | Calcium | en_US |
| dc.subject | 4-Nitrobenzoate | en_US |
| dc.subject | Methylformamide | en_US |
| dc.subject | Benzamide | en_US |
| dc.title | On the syntheses and structures of two calcium coordination polymers containing terminal amide ligands | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.56A(04) [April 2017] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 56A(4) 387-393.pdf | Main Article | 912.02 kB | Adobe PDF | View/Open |
| IJCA 56A(4) 387-393_Suppl Data.pdf | Supplementary Data | 496.48 kB | Adobe PDF | View/Open |
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