Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/41203
Full metadata record
DC FieldValueLanguage
dc.contributor.authorSrinivasan, Bikshandarkoil R-
dc.contributor.authorDhavskar, Kiran T-
dc.date.accessioned2017-04-11T10:51:36Z-
dc.date.available2017-04-11T10:51:36Z-
dc.date.issued2017-04-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.identifier.urihttp://nopr.niscair.res.in/handle/123456789/41203-
dc.description387-393en_US
dc.description.abstractThe syntheses and crystal structure of the calcium coordination polymers [Ca(NMF)2(4-nba)2] 1 (4-nba = 4-nitrobenzoate; NMF=N-methylformamide) and [Ca(BA)2(4-nba)2] 2 (BA= benzamide) is reported. A unique μ2-η1: η1 bridging bidentate 4-nba ligand links the hexacoordinated Ca(II) ions situated on a special position in both compounds into a one-dimensional (1-D) chain with Ca···Ca separations of 5.561 and 5.482 respectively. Each Ca(II) in the chain is bonded to a pair of symmetry related terminal amide ligands (NMF in 1; BA in 2) which are disposed trans to each other. A comparative study of several 4-nitrobenzoates of calcium is described.en_US
dc.language.isoen_USen_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.56A(04) [April 2017]en_US
dc.subjectCoordination chemistryen_US
dc.subjectCoordination polymersen_US
dc.subjectCalciumen_US
dc.subject4-Nitrobenzoateen_US
dc.subjectMethylformamideen_US
dc.subjectBenzamideen_US
dc.titleOn the syntheses and structures of two calcium coordination polymers containing terminal amide ligandsen_US
dc.typeArticleen_US
Appears in Collections:IJC-A Vol.56A(04) [April 2017]

Files in This Item:
File Description SizeFormat 
IJCA 56A(4) 387-393.pdfMain Article912.02 kBAdobe PDFView/Open
IJCA 56A(4) 387-393_Suppl Data.pdfSupplementary Data496.48 kBAdobe PDFView/Open


Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.