Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/41257
Title: Kinetics of oxidation of chromium(lll) by N-bromosuccinimide in aqueous alkaline medium
Authors: Kamble, D L
Hugar, G H
Nandibewoor, S T
Issue Date: Feb-1996
Publisher: NISCAIR-CSIR, India
Abstract: The title reaction is first order in [N-bromosuccinimide] (NBS), fractional order in [chromium(III)] and inverse fractional order in [OH-]. A negative temperature effect is noticed. The active species of chromium(lll) and NBS are Cr(OH) and HOBr respectively. A mechanism has been proposed and the reaction constants are derived.
Page(s): 144-147
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.35A(02) [February 1996]

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