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http://nopr.niscpr.res.in/handle/123456789/41257| Title: | Kinetics of oxidation of chromium(lll) by N-bromosuccinimide in aqueous alkaline medium |
| Authors: | Kamble, D L Hugar, G H Nandibewoor, S T |
| Issue Date: | Feb-1996 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The title reaction is first order in [N-bromosuccinimide] (NBS), fractional order in [chromium(III)] and inverse fractional order in [OH-]. A negative temperature effect is noticed. The active species of chromium(lll) and NBS are Cr(OH) and HOBr respectively. A mechanism has been proposed and the reaction constants are derived. |
| Page(s): | 144-147 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.35A(02) [February 1996] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 35A(2) 144-147.pdf | 884.44 kB | Adobe PDF | View/Open |
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and HOBr respectively. A mechanism has been proposed and the reaction constants are derived.