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http://nopr.niscpr.res.in/handle/123456789/41269| Title: | A low-spin carboxyl-bonded iron(III) complex |
| Authors: | Karmakar, Soma Chakravorty, Animesh |
| Issue Date: | Feb-1996 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The ligand HON =C(Ph)N =N - C6H4CO2H (H2L) has afforded the low-spin (S = 1/2) iron(lll) complex, Et4N[Fe(PhL)2] which has been structurally characterised revealing the presence of cis-FeN4O2 coordination sphere. Carboxyl-bonded low-spin iron(lll) species are very rare. Spin-pairing contracts metal radius, the Fe - N and Fe - O lengths being significantly shorter than those in representative high-spin complexes. |
| Page(s): | 85-86 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.35A(02) [February 1996] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 35A(2) 85-86.pdf | 503.43 kB | Adobe PDF | View/Open |
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