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http://nopr.niscpr.res.in/handle/123456789/41276Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Ghosh, A K | - |
| dc.contributor.author | Sengupta, P S | - |
| dc.contributor.author | De, G S | - |
| dc.date.accessioned | 2017-04-18T11:29:26Z | - |
| dc.date.available | 2017-04-18T11:29:26Z | - |
| dc.date.issued | 1997-07 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://nopr.niscair.res.in/handle/123456789/41276 | - |
| dc.description | 611-613 | en_US |
| dc.description.abstract | The interaction of I-cysteine with hydroxopentaaquarhodium (lIl) has been studied spectrophotometrically as a function of pH, [entering ligand], [substrate] and temperature following the absorption of I-cysteine substituted product at 352 nm. The reaction rate increases with increase in [ligand] and approaches a limiting rate. The values of ΔH¹ (72.6 ± 0.6 kJ) and ΔS¹ (- 91.0 ± 1.8 JK -1 mol- 1) have been calculated from Eyring plot and compared with aqua exchange and analogous ligand substitution processes. An associative interchange mechanism with the ligand participation in the TS is proposed. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.36A(07) [July 1997] | en_US |
| dc.title | Interaction of 1-cysteine with hydroxopentaaquarhodium(III) ion: Kinetic and mechanistic studies | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.36A(07) [July 1997] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 36A(7) 611-613.pdf | 659.16 kB | Adobe PDF | View/Open |
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