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http://nopr.niscpr.res.in/handle/123456789/41315| Title: | σ-Bonded organometallic complexes of iron and cobalt derived from 2-bromomethylnaphthalene |
| Authors: | Alam, F R Azam, K A Kabir, S E Ullah, S S |
| Issue Date: | Apr-1996 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The monoanionic metal carbonylate Na[Fe(η5-C5H5) (CO)2] reacts with 2-bromomethylnaphthalene at ambient temperature to give [(σ-C10H7CH2)Fe(η5-C5H5)(CO)2] (I) whereas with Na[Co(CO)4] at room temperature [(σ-C10H7CH2)Co(CO)4](II) is obtained. Irradiation of (I) yields [(η5-C5H5)Fe(CO)2]2 (III) and C10H7CH2CH2C10H7 (IV). The compounds have been characterized by IR. PMR, mass spectroscopic data and elemental analysis. |
| Page(s): | 317-319 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.35A(04) [April 1996] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 35A(4) 317-319.pdf | 743.6 kB | Adobe PDF | View/Open |
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