Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/41325| Title: | Electrochemical oxidation of 2-mercaptobenzoxazole |
| Authors: | Goyal, Rajendra N Verma, Madhu Shri |
| Issue Date: | Apr-1996 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Electrochemical oxidation of 2-mercaptobenzoxazole has been studied in the phosphate buffers of pH 2.5-10.3 at solid electrodes. In the entire pH range a well-defined oxidation peak (Ia) was observed. The peak potential of this peak is linearly dependent on pH and the Ep-pH plot shows a break around pH 7.8, corresponding to the pka of the species. At pH ≥ 7.0 an additional oxidation peak (IIa) has been noticed. The electrode process is found to involve adsorption complications at PGE and the change in Ep with log v indicated radical radical coupling. The products of oxidation have been separated and characterized by using m.p., 1H NMR and mass spectra. |
| Page(s): | 281-287 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.35A(04) [April 1996] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 35A(4) 281-287.pdf | 1.51 MB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.