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http://nopr.niscpr.res.in/handle/123456789/41337| Title: | Synthesis and characterization of [Ru(η6-C6Me6)Cl2 (CNPy)] and [Cl2(η6-C6Me6)Ru-(µ-CNPy)-Ru(η6-C6Me6)Cl2] and reactivity of [Ru(η6-C6Me6)Cl2(CNPy)] with various bases |
| Authors: | Pandey, D S Sahay, A N Agarwala, U C |
| Issue Date: | May-1996 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Reactions of [{Ru(η6-C6Me6)CI2}2] with 4-cyanopyridine lead to the formation of neutral mono and dimeric complexe viz., [Ru(η6-C6Me6)CI2(CNPy)] (I) and [CI2(η6-C6Me6)Ru-(µ-CNPy)-Ru(η6-C6Me6)CI2] (II). Complex (I) undergoes metathetical reactions with EPh3 (E = P, As & Sb) and N-donor heterocyclic bases yielding corresponding substitutional products which have been characterized by elemental analyses and spectroscopic : (IR, UV/vis, 1H and 13CNMR) studies. |
| Page(s): | 434-437 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.35A(05) [May 1996] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 35A(5) 434-437.pdf | 369.35 kB | Adobe PDF | View/Open |
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