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http://nopr.niscpr.res.in/handle/123456789/41400Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Ramachandran, M S | - |
| dc.contributor.author | Easwaramoorthy, D | - |
| dc.contributor.author | Sayeekannan, R | - |
| dc.contributor.author | Vasanthkumar, S | - |
| dc.date.accessioned | 2017-04-24T06:16:55Z | - |
| dc.date.available | 2017-04-24T06:16:55Z | - |
| dc.date.issued | 1996-08 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://nopr.niscair.res.in/handle/123456789/41400 | - |
| dc.description | 696-700 | en_US |
| dc.description.abstract | The kinetics of oxidation of amino acids by bromine in aqueous, perchloric acid medium at 35°C has been studied. Based on the experimental results, a reaction scheme is proposed in which the active oxidants are bromine and HOBr. The electrophilic attack of bromine occurs at the carboxylate (- COO -) group. HOBr reacts with the amino acids through the a-hydrogen atom via hydride ion transfer or abstraction. The a-substituent plays a vital role in accelerating the rate limiting step. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.35A(08) [August 1996] | en_US |
| dc.title | Role of a-substituent on the oxidation of a-amino acids by bromine in acid medium | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.35A(08) [August 1996] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 35A(8) 696-700.pdf | 811.42 kB | Adobe PDF | View/Open |
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