Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/41479
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dc.contributor.authorRajendiran, Narayanasamy-
dc.contributor.authorSwaminathan, Meenakshisundaram-
dc.date.accessioned2017-04-27T06:43:15Z-
dc.date.available2017-04-27T06:43:15Z-
dc.date.issued1996-10-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.identifier.urihttp://nopr.niscair.res.in/handle/123456789/41479-
dc.description818-824en_US
dc.description.abstract2-Phenoxyaniline (2POA) shows a dual fluorescence in hydrogen bonding solvents. The increase in Stokes shift with increase in polarity is much more for longer wavelength abnormal fluorescence band (FA) than for shorter wavelength fluorescence band (FN). It is found that FA band arises only due to bulk properties of solvent and not due to complex formation. A mechanism involving twisted intramolecular charge transfer (TICT) state is proposed for the dual fluorescence of 2POA. pHstudies indicate that the stretched sigmoid curve obtained for the neutral-monocation equilibrium is due to overlap of proton induced fluorescence quenching and monocation formation curves.en_US
dc.language.isoen_USen_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.35A(10) [October 1996]en_US
dc.titleDual fluorescence of 2-phenoxyanilineen_US
dc.typeArticleen_US
Appears in Collections:IJC-A Vol.35A(10) [October 1996]

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