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http://nopr.niscpr.res.in/handle/123456789/41495| Title: | Kinetics of oxidation of tris-(2,2' -bipyridyI)cobalt(II) by iron(III)- 2,2' -bipyridyl complex-Micellar effect of sodium dodecylsulphate |
| Authors: | Rao, P V Subba Rao, G Krishna Ramakrishna, K Rambabu, G Satyanarayana, A |
| Issue Date: | Nov-1996 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | lron(III)-2,2' -bipyridyl complex obtained, in situ, by direct mixing of iron(III) and 2,2' -bipyridyl, oxidises I Co(Bipy) and the reaction is markedly accelerated by sodium dodecylsulphate. The rate- [surfactant] profile exhibits a maximum. The kinetic analysis of the micellar effect has been carried out using Berezin's approach. The binding constants of 2,2¢-bipyridyl and Co(Bipy) have been determined. |
| Page(s): | 969-973 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.35A(11) [November 1996] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 35A(11) 969-973.pdf | 986.12 kB | Adobe PDF | View/Open |
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