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http://nopr.niscpr.res.in/handle/123456789/41499| Title: | Synthesis, characterization and redox properties of ruthenium (II) phenolato Schiff base mixed ligand complexes |
| Authors: | Rao, P S Thakur, G A Lahiri, G K |
| Issue Date: | Nov-1996 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Mixed ligand phenolato Schiff base complexes of ruthenium (II) of the types [Ru(pap)2L]CIO4, [pap = 2-(phenylazo) pyridine; L= deprotonated form of HL ligand, HO-C6H4-CH = N-C6H4-(R), where R=H, Me, OMe, Cl, NO2] and [Ru(bpy)2L2]CIO4.H2O (where bpy=2,2'-bipyridine) have been synthesised and characterised. The complexes are diamagnetic and in acetonitrile solution they behave as 1:1 electrolyte. All the complexes show strong MLCT transitions in the visible region 400- 800 nm. The redox properties of all these complexes have also been studied. |
| Page(s): | 946-951 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.35A(11) [November 1996] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 35A(11) 946-951.pdf | 1.09 MB | Adobe PDF | View/Open |
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