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http://nopr.niscpr.res.in/handle/123456789/41537| Title: | Preparation of surface-enriched polymersupported phase transfer catalysts and kinetics of dichlorocarbene addition to cycylohexene using 50 % NaOH. |
| Authors: | Balakrishnan, T Murugan, E |
| Issue Date: | Aug-1997 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Different types of surface-enriched polymersupported (bead shaped) catalysts have been synthesized using vinyltoluene as a functionality. This provides a free and easy contact of substrate on to the active- site of the catalyst. The comparative efficacy of the catalysts is tested by carrying out the reactions like dichlorocarbene addition to cyclohexene and alkylation of phenylacetone with n-butyl bromide. The catalyst labelled 3Vf has been chosen to study the detailed kinetics of dichlorocarbene addition to cyclohexene. |
| Page(s): | 697-700 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.36A(08) [August 1997] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 36A(8) 697-700.pdf | 770.49 kB | Adobe PDF | View/Open |
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