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http://nopr.niscpr.res.in/handle/123456789/41555| Title: | Kinetics of oxidation of 12-tungstocobaltate(II) ion by peroxodiphosphate ion in perchloric acid and demonstration of Ag(I)-catalysis |
| Authors: | Mehrotra, Raj N Goyal, Bharti Bhati, Sangeeta Prakash, Aditya |
| Issue Date: | Aug-1997 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Two moles of 12-tungstocobaltate(II) ion, [Co(II)W12O40]6-,abbreviated as [Co(II)W]6-, are oxidised by each mole of peroxodiphosphate ion. The reaction is first-order in each reagent. The empirical rate law (i) is shown to hold for the Ag(I)-catalysed reaction.... |
| Page(s): | 657-661 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.36A(08) [August 1997] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 36A(8) 657-661.pdf | 927.46 kB | Adobe PDF | View/Open |
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