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http://nopr.niscpr.res.in/handle/123456789/41587Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Singh, Ashok Kumar | - |
| dc.contributor.author | Bisai, Shambhunath | - |
| dc.contributor.author | Chakravarty, Biswanath | - |
| dc.date.accessioned | 2017-05-02T07:15:00Z | - |
| dc.date.available | 2017-05-02T07:15:00Z | - |
| dc.date.issued | 1997-09 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://nopr.niscair.res.in/handle/123456789/41587 | - |
| dc.description | 769-771 | en_US |
| dc.description.abstract | Acid-catalysed bridge cleavage reaction ofthe compound [(BigHb Co-µ-(OH)2 - Co(BigH)24+ has been investigated spectrophotometrically with both perchloric and nitric acids in the temperature range 42°-60°. In acid medium, rupture of first bridge is rate determining while breakage of the second bridge is fast. Bridge cleavage reaction proceeds only through the acid-catalysed path. Rate equations, rate constants and activation parameters (ΔH‡ ,44.3±3.3 kJ mol-1, ΔS‡ -188±18 JK-1 mol-1) are similar in both the perchloric and the nitric acids. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.36A(09) [September 1997] | en_US |
| dc.title | Studies on the bridge cleavage reactions of di- µ -hydroxotetrakistbiguanide)dicobalt(III) ion in the presence of perchloric and nitric acids | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.36A(09) [September 1997] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 36A(9) 769-771.pdf | 763.22 kB | Adobe PDF | View/Open |
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