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http://nopr.niscpr.res.in/handle/123456789/41613| Title: | Synthesis, characterization and the crystal structure of dicopper complex [Cu2(C6H4COO)4 (C8H11N)2 ] |
| Authors: | Mei, Wang Dong Yu, Xue Bao Na, Yang Rui Man, Jin Dou |
| Issue Date: | Oct-1997 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Dibenzoyl peroxide undergoes oxidative addition to metallic copper with 2,4,6-trimethylpyridine in acetone solvent and affords the binuclear complex [CU2(C6H5COO)4(C5H11N)2]. This complex has been characterized by elemental analysis. IR and UV- vis spectroscopies. thermal analysis and X-ray diffraction techniques. The X-ray studies show that the structure of the complex is monoclinic, space group, P21/N, with cell parameters, a=10.499(4), b=10.666(6), c=18.109(3)Å, β=92.92(2)o , 1'=2025.2 Å3 Z=2, Dc=1.398g.cm-3, R=0.068 and Rw=0.075. Each copper ion is coordinated by four bridging bidentate benzoate ligands and one 2,4,6-trimethylpyridine to form binuclear molecule. |
| Page(s): | 887-890 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.36A(10) [October 1997] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 36A(10) 887-890.pdf | 751.2 kB | Adobe PDF | View/Open |
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