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http://nopr.niscpr.res.in/handle/123456789/41670| Title: | Kinetics and mechanism of oxygen atom transfer reaction in the formation of Ruv = O(EDTA)-1 complex: A reactivity scale for the oxidants |
| Authors: | Chatterjee, Debabrata Padhiyar, H. J. |
| Issue Date: | Nov-1997 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The oxidation of .Ru111 (EDTA) (H20)- 1 with single oxygen atom donors (viz. H2O2, PhIO, KHSO5, NaOCI, Py-N-oxide) has been studied spectrophotometrically by following the development of characteristic peak of the Ruv = O (EDT A)- oxo-complex 2. The activation parameters have been' calculated in terms of a mechanism involving an intramolecular oxygen atom transfer from oxidant to complex 1. A reactivity scale has been set for the oxidants ClO-, PyO. H2O2, KHSO5 and C6H5IO on the basis of ΔG values. |
| Page(s): | 956-958 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.36A(11) [November 1997] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 36A(11) 956-958.pdf | 282.42 kB | Adobe PDF | View/Open |
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