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http://nopr.niscpr.res.in/handle/123456789/41746| Title: | Ruthenium(II) hydrido complexes of S-methyldithiocarbazates |
| Authors: | Maurya, M R Unny, I R Alekar, N A Gopinathan, S Gopinathan, C |
| Issue Date: | Dec-1997 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Reactions of [RuHCI(CO)(PPh3)3] and [RuH2(CO)(PPh3) 3] with schiff bases (HL) derived from S-methyldithiocarbazate and pyridine-Z-aldchyde, 2-acetylpyridine, thiophene-2-aldehyde. 2- acetyl1hiophene and furan-z-aldehyde lead to the formation of neutral complexes of the type [RuX(CO)(PPh3)2L] (X = H or CI). The probable stereochemistries of the complexes have been established on the basis of elemental analysis. IR, 1H and 13C NMR studies. The triphenylphosphines are trans leaving CO and H or Cl cis to each other in the complexes. |
| Page(s): | 1058-1062 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.36A(12) [December 1997] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 36A(12) 1058-1062.pdf | 429.45 kB | Adobe PDF | View/Open |
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