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http://nopr.niscpr.res.in/handle/123456789/41762| Title: | Trichloro-niobium(V) and -tantalum(V) bis-O,O' -dialkyl dithiophosphates |
| Authors: | Pandey, SushiI K Srivastava, Ghanshyam Mehrotra, Ram C |
| Issue Date: | Jan-1991 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Trichloro-niobium(V) and -tantalum(V) bis-dialkyl dithiophosphates, Cl3M[S2P(OR)2/2 (where M =Nb or Ta; R =Prn, Pri, Bui & Ph) have been synthesized by stoichiometric reactions of the metal(V) chlorides with sodium/ammonium salts of dialkyl dithiophosphoric acids. The complexes are orange/yellow viscous liquids, soluble in polar organic solvents. These have been characterized by elemental analysis and spectral studies such as IR and NMR (1H, 13C & 31P). A seven- coordinated structure has been suggested for these compounds. |
| Page(s): | 92-94 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.30A(01) [January 1991] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 30A(1) 92-94.pdf | 656.97 kB | Adobe PDF | View/Open |
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