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http://nopr.niscpr.res.in/handle/123456789/41842| Title: | Oxidation of diphenylamines by iodate - A kinetic study |
| Authors: | Brahrnaiah, A Manikyamba, P |
| Issue Date: | Mar-1991 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Oxidation of diphenylamines (DPA) by iodate in aqueous methanol (70%, v/v) at 303 K is first order in [oxidant] and fractional order in [DPA] and is acid-catalysed. There is a dipole-dipole interaction between the oxidant and DPA. The substituent effect on the rate of reaction shows that electron- releasing groups on the benzene ring enhance the rate and electron-withdrawing groups retard the rate compared to the unsubstituted DPA. The product identified is the corresponding carbazole. Thermodynamic parameters are calculated and a suitable mechanism is proposed. |
| Page(s): | 247-251 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.30A(03) [March 1991] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 30A(3) 247-251.pdf | 328.33 kB | Adobe PDF | View/Open |
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