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http://nopr.niscpr.res.in/handle/123456789/41843| Title: | Kinetics and mechanism of cooxidation of oxalic acid and arsenic(III) by chlorochromate in aqueous acetic acid |
| Authors: | Sambrani, M I Raju, J R |
| Issue Date: | Mar-1991 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The influence of oxalic acid on chromium(VI) oxidation of arsenic(III) is studied in the presence of chloride ion in 60% aqueous acetic acid and I = 0.80mol dm-3 (NaCIO4). It is found that both arsenic(III) and oxalic acid are oxidised concertedly in a three equivalent step. It has been found that one mole of Cr(VI) oxidises one equivalent of oxalic acid and two equivalents of arsenic(III). The details of such a process are discussed. |
| Page(s): | 243-246 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.30A(03) [March 1991] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 30A(3) 243-246.pdf | 315.68 kB | Adobe PDF | View/Open |
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