Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/41890| Title: | Methyl nitrene: Thermochemistry and kinetics of its rearrangement to methyleneimine |
| Authors: | Kakkar, Rita Walia, Vibha |
| Issue Date: | Apr-1991 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The thermal unimolecular isomerisation of methylnitrene to methyleneimine has been studied, and the macroscopic thermodynamic and kinetic properties have been calculated using the vibrational frequencies and rotational constants evaluated theoretically. The high pressure rate constants have been calculated and the fall-off behaviour has been studied using the calculated reactant and transition state properties. Kinetic isotope effects on the reaction have also been studied. The effects of fluorine substitution on the thermochemical and kinetic parameters have also been investigated. |
| Page(s): | 308-312 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.30A(04) [April 1991] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 30A(4) 308-312.pdf | 982.87 kB | Adobe PDF | View/Open |
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