Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/41916| Title: | Electroreduction of 2-(3-nitro-1-phenylhydrazono)dimedone in buffered methanolic solutions |
| Authors: | Vasudevan, D Venkatachalam, C S Kalidas, C |
| Issue Date: | Jun-1991 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The electro reduction of 2-(3-nitro-1-phenylhydrazono) dimedone (3-NO2-1-PHD) has been carried out in buffered 60% (v/v)methanolic solutions in the pH range 2.0-12.0. The compound gives two diffusion-limited irreversible DC polarographic waves/AC peaks. Cyclic voltammetric studies show two cathodic peaks in the forward scan, the first peak correspooding to the reduction of the nitro group and the second to that of the hydrazono group. The results of the present study clearly indicate the existence of the title compound in the hydrazono form, which had been a matter of controversy. |
| Page(s): | 561-563 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.30A(06) [June 1991] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 30A(6) 561-563.pdf | 216.27 kB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.