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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Balakrishna, M S | - |
| dc.contributor.author | Krishnamurthy, S S | - |
| dc.date.accessioned | 2017-05-25T04:58:06Z | - |
| dc.date.available | 2017-05-25T04:58:06Z | - |
| dc.date.issued | 1991-06 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://nopr.niscair.res.in/handle/123456789/41924 | - |
| dc.description | 536-537 | en_US |
| dc.description.abstract | The reaction of the diphosphazane ligand, PhN{P(OPh)2}2 with cyclopentadienyliron dicarbonyl dimer, [Fe(CO) (CO)2]2 in boiling benzene yields two complexes 1 and 2 (in 75% and 5% yields respectively) which are separated by fractional crystallization. NMR (1H and 31P) and IR spectroscopic data indicate that one of the complexes, i.e, 1 is a simple substitution product of the formula [Fe2(CO)2(CO)2 {m-PhN(P(OPh)2)2}] whereas the other, i.e., 2 is an unusual isomeric complex, containing bridging P(OPh)2 and PhN =P(OPh)2 units that are formed by the cleavage of one of the P - N bonds of the diphosphazane ligand. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.30A(06) [June 1991] | en_US |
| dc.title | Organometallic derivatives of diphosphazanes: Part 3†-The reaction of PhN{P(OPh)2}2 with [Fe(η5-C5H5)(CO)2]2, unusual cleavage of a P-N bond to yield a complek containing P(OPh)2 and PhNP(OPh)2 units | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.30A(06) [June 1991] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 30A(6) 536-537.pdf | 158.94 kB | Adobe PDF | View/Open |
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