Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/42037
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dc.contributor.authorRao, (Miss) Indu-
dc.contributor.authorMishra, S K-
dc.contributor.authorSharma, P D-
dc.date.accessioned2017-05-30T07:16:09Z-
dc.date.available2017-05-30T07:16:09Z-
dc.date.issued1991-09-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.identifier.urihttp://nopr.niscair.res.in/handle/123456789/42037-
dc.description773-776en_US
dc.description.abstractThe reaction between thallium(III) and malonic acid (H2ma) studied in acid perchlorate medium corresponds to th stoichiometry as represented by the equation
3TI(III) + CH2(COOH)2 ®3TI(I) + HCOOH + CO2 + 6H+
Thallium(III) forms an intermediate complex and the reduction of thallium(III) occurs via an internal redox reaction of the complex. A suitable mechanism has been suggested and the energy and entropy of activation of the rat determining step have been calculated.
en_US
dc.language.isoen_USen_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.30A(09) [September 1991]en_US
dc.titleelectron-transfer reactions of Aquothallium(III) and coordinated thallium(III), oxidation of malonic acid with thallium(III) in perchlorate mediumen_US
dc.typeArticleen_US
Appears in Collections:IJC-A Vol.30A(09) [September 1991]

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