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http://nopr.niscpr.res.in/handle/123456789/42202| Title: | Preparation and properties of heterobimetallic alkoxides of iron(III) with aluminium(III), niobium and tantalum |
| Authors: | Shah, A Singh, J Singh, A Mehrotra, R C |
| Issue Date: | Dec-1991 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Reactions of anhydrous FeCI3; with K{AI(OPri)4}.and K{M(OPri)6} (M = Nb, Ta) in 1:3 molar ratios in isopropyl alcohol-benzene mixture result in products having the compositions, [FelAl(OPri)4}3(1a) and [Fe{M(OPri)6}3 (2a and 3a) respectively. Reactions of these products with alcohols of varying steric bulk yield mixed alkoxy-isopropoxy bimetallic complexes. All these bimetallic alkoxide derivatives have been characterized by elemental/group analysis and molecular weight determinations as well as by infrared, visible spectral and magnetic studies. |
| Page(s): | 1018-1023 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.30A(12) [December 1991] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 30A(12) 1018-1023.pdf | 3.18 MB | Adobe PDF | View/Open |
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