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http://nopr.niscpr.res.in/handle/123456789/42315Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Kalpana, A | - |
| dc.contributor.author | Akilandeswari, L | - |
| dc.date.accessioned | 2017-06-29T07:38:33Z | - |
| dc.date.available | 2017-06-29T07:38:33Z | - |
| dc.date.issued | 2017-06 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://nopr.niscair.res.in/handle/123456789/42315 | - |
| dc.description | 610-615 | en_US |
| dc.description.abstract | The current work focuses on manifold magnification of tripodal rotational barrier of Cr(CO)3 which is haptotropically bound to the arene ring with variety of hetero substitution (boron/phosphorus). The study shows that the differential electronegativities of boron and phosphorus can be harnessed to manipulate the torsional barrier, enabling hundred 200-fold enhancement of barrier to nearly free tripodal rotation of Cr(CO)3 in arene moiety. Insights obtained by density functional studies are supported by natural bond orbital analysis. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.56A(06) [June 2017] | en_US |
| dc.subject | Tripodal rotational barrier | en_US |
| dc.subject | Tricarbonyl chromium complexes | en_US |
| dc.subject | Carbonyl complexes | en_US |
| dc.subject | Chromium | en_US |
| dc.subject | Boron | en_US |
| dc.subject | Phosphorus | en_US |
| dc.subject | Density functional calculations | en_US |
| dc.subject | Natural bond orbital analysis | en_US |
| dc.subject | Torsional switches | en_US |
| dc.title | Tuning the tripodal rotational barrier in η6- chromiumtricarbonyl heteroarenes – A step towards torsional switches | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.56A(06) [June 2017] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 56A(6) 610-615.pdf | 163.36 kB | Adobe PDF | View/Open |
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