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http://nopr.niscpr.res.in/handle/123456789/43729| Title: | Synthesis and spectral properties of 1, 3-bis(2-benzirnidazyl)benzene and its N-methylated derivative-Reactions with some acids and cobalt(II) salts |
| Authors: | Gayathri, V Shashikala, N Gowda, N M Nanje Reddy, G K N |
| Issue Date: | Jan-1993 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Syntheses of 1,3-bis(2-benzimidazyl)benzene (bBzlH2Bz) and its N-methylated derivative (NMebBzlBz) as well as their acid adducts and a few complexes of cobalt(ll), CoX2L (X = halogen; L= N-heterocycle) and [CoL2](CIO4)2, have been described. The heterocycles have been characterised by IR, electronic and NMR spectral data The electronic and magnetic susceptibility data suggest tetrahedral geometry for CoX2L and [COL2] (ClO4 (L= bBzIH2Bz or N-MebBzlBz), trigonal-bipyramidal for CoX2(N-MebBzlPy) [N-MebBzlPy = 2,6-bis(N-methylbenzimidazyl)pyridine and square-pyramidal geometry for [Co(N-MebBzlPy)2]X2 (X = l or CIO4) complexes. |
| Page(s): | 33-38 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.32A(01) [January 1993] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 32A(1) 33-38.pdf | 465.25 kB | Adobe PDF | View/Open |
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