Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/43731| Title: | Investigations of transients produced on reactions of OH radicals with azobenzene in aqueous solutions |
| Authors: | Panajkar, M S Mohan, Hari |
| Issue Date: | Jan-1993 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The OH radicals are observed to react with azobenzene with a bimolecular rate constant of 2.0 x 1010dm3 mol-1 s-1. About 40% of (OH radicals add to benzene ring producing a transient band with λmax = 330nm and ~ 60% add to - N = N - double bond forming a transient band with λmax = 420 (ε = 10,270 dm3 mol-1 cm-1). The OH radicals fail to undergo one electron transfer reaction with azobenzene. Steady state gamma-radiolysis shows the formation of a product absorbing in the 260-280 nm region. |
| Page(s): | 25-27 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.32A(01) [January 1993] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 32A(1) 25-27.pdf | 207.26 kB | Adobe PDF | View/Open |
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