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http://nopr.niscpr.res.in/handle/123456789/43747Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Ghosh, Kallol K | - |
| dc.contributor.author | Rajput, Surendra K | - |
| dc.contributor.author | Krishnani, Kishore K | - |
| dc.date.accessioned | 2018-03-09T09:01:05Z | - |
| dc.date.available | 2018-03-09T09:01:05Z | - |
| dc.date.issued | 1993-02 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://nopr.niscair.res.in/handle/123456789/43747 | - |
| dc.description | 139-142 | en_US |
| dc.description.abstract | The rate of hydrolysis of 3-chlorobenzohydroxamic acid [3-Cl-C6H4.CO.NHOH] has been measured over a wide range of acidities in hydrochloric, sulfuric and perchloric acids in 10% (v/v) DMSO-Water at 55oC. The kinetics have been analysed by Bunnett, Bunnett-Olsen and Cox-Yates excess acidity treatments. Kinetic solvent isotope, salt and temperature effects have also been probed. The mechanism of the acid catalysed hydrolysis is postulated as involving two steps: a rapid protonation and a rate-determining A-2 nucleophilic attack by water. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.32A(02) [February 1993] | en_US |
| dc.title | Kinetic and mechanistic study of acid-catalysed hydrolysis of 3-chlorobenzohydroxamic acid | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.32A(02) [February 1993] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJC 32A(2) 139-142.pdf | 319.73 kB | Adobe PDF | View/Open |
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