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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Basak, Samarendra | - |
| dc.contributor.author | Banerjea, Debabrata | - |
| dc.date.accessioned | 2018-03-09T09:09:30Z | - |
| dc.date.available | 2018-03-09T09:09:30Z | - |
| dc.date.issued | 1993-02 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://nopr.niscair.res.in/handle/123456789/43749 | - |
| dc.description | 129-133 | en_US |
| dc.description.abstract | Kinetics of dissociation of the schiff base complexes of uranium(VI), (I) UO2(H2salen) (NO3)2, (II) UO2(H2baen) (NO3)2 and (III) UO2(salgly) (H2O) in acidic ethanol-water solution and of (IV) a 1:1 complex formed by uranium(VI) with chromotropic acid in acidic aqueous medium leading to formation of solvated UO ion have been studied by stopped-flow spectrophotometry. For all the complexes dissociation involves concurrent acid independent and acid dependent paths: kobs = ko + kH[H+]. Activation parameters corresponding to ko and kH for all the complexes have been determined and plausible mechanisms for dissociation have been suggested. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.32A(02) [February 1993] | en_US |
| dc.title | Kinetic studies on the acid assisted dissociation of some uranium(VI) complexes in solution | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.32A(02) [February 1993] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJC 32A(2) 129-133.pdf | 395.67 kB | Adobe PDF | View/Open |
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