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http://nopr.niscpr.res.in/handle/123456789/43773| Title: | Zirconium(IV) and thorium (IV) bis(fluorosulphuryl)imides: Preparation and characterization |
| Authors: | Vij, Ashwani Singh, Sukhjinder Kaur, Gurmeen Verma, R D |
| Issue Date: | Mar-1993 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Metal (IV) bis(fluorosulphuryl) imides [M=Zr(IV) and Th(IV)] have been prepared by reacting the corresponding trifluoroacetates with HN(SO2F)2 at 100-130°C for ~ 10 hours. These are thermally stable, white hygroscopic solids (m.p. > 210°C) and are insoluble in common organic solvents and HN(SO2F)2. These properties reflect their polymeric nature. M[N(SO2F)2]4 form coordination complexes with some nitrogen and oxygen donors. |
| Page(s): | 232-235 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.32A(03) [March 1993] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 32A(3) 232-235.pdf | 301.53 kB | Adobe PDF | View/Open |
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