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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Srinivasan, Vangalur S | - |
| dc.contributor.author | Ramakrishnan, Kalyani | - |
| dc.date.accessioned | 2018-03-13T06:59:06Z | - |
| dc.date.available | 2018-03-13T06:59:06Z | - |
| dc.date.issued | 1993-04 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://nopr.niscair.res.in/handle/123456789/43806 | - |
| dc.description | 338-340 | en_US |
| dc.description.abstract | The kinetics of regeneration of carbonyl compounds from anil of benzaldehyde and benzophenone by MnIII(OAc)3 have been studied at 29 ± 0.1ᵒC in aq. acetic acid (76%, v/v). The corresponding aldehyde/ketone is formed in about 96% yield along with nearly 48% of
azobenzene in about 3-4 hr. One mol of anil consumes nearly 2 mol of MnIII(OAc)3 for the reaction. The reaction is less susceptible to the electronic influence of substituents
on both benzaldehyde and aniline portions. A mechanism involving addition of MnIII(OAc)3 to C = N in the rate determining step has been envisaged to account for the results. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.32A(04) [April 1993] | en_US |
| dc.title | Facile regeneration of carbonyl compounds from anils by manganese(III) triacetate- A kinetic study | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.32A(04) [April 1993] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 32A(4) 338-340.pdf | 171.27 kB | Adobe PDF | View/Open |
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