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http://nopr.niscpr.res.in/handle/123456789/43945| Title: | Kinetics of oxidation of bisulphite ion by iron (III) in the presence of 1,10-phenanthroline |
| Authors: | Mohapatra, S K |
| Issue Date: | Aug-1993 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The title reaction has been investigated under pseudo-unimolecular conditions with [phen] > [HSO ] > [Fe(III)]. The reaction obeys first order kinetics in [Fe(III)]. The kinetics is interpreted in terms of an inner-sphere reduction of Fe(phen) via formation of the reactive intermediate Fe(phen)2-(SO3H)2+. |
| Page(s): | 709-710 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.32A(08) [August 1993] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 32A(8) 709-710.pdf | 142.83 kB | Adobe PDF | View/Open |
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] > [Fe(III)]. The reaction obeys first order kinetics in [Fe(III)]. The kinetics is interpreted in terms of an inner-sphere reduction of Fe(phen)
via formation of the reactive intermediate Fe(phen)2-(SO3H)2+.