Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/44046
Title: Reductimetric determination of some quinones with iron(II)
Authors: Raju, K Vijaya
Raju, G Bangar
Yadav, M Rajasekhar
Issue Date: Nov-1993
Publisher: NISCAIR-CSIR, India
Abstract: A simple and convenient reductimetric titration method has been developed for the determination of some quinones using iron(II) as a reductant in buffer medium (optimum pH 4.0-5.0) in the presence of oxalate ions (optimum concentration 0.06-0.12 M). The end-point can be determined either potentiometrically or visually using some oxazine dyes as indicator. In these titrations, the quinones as well as the indicators are reduced in a two-electron reduction step to their corresponding hydroquinones and leuco-bases respectively. The function of pH and oxalate ions in the reaction medium has also been discussed.
Page(s): 1012-1014
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.32A(11) [November 1993]

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