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http://nopr.niscpr.res.in/handle/123456789/44073Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Hugar, G H | - |
| dc.contributor.author | Nandibewoor, S T | - |
| dc.contributor.author | Raju, J R | - |
| dc.date.accessioned | 2018-03-26T08:23:04Z | - |
| dc.date.available | 2018-03-26T08:23:04Z | - |
| dc.date.issued | 1993-12 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://nopr.niscair.res.in/handle/123456789/44073 | - |
| dc.description | 1095-1098 | en_US |
| dc.description.abstract | Chromium(VI) oxidation of antimony(III) in an alkaline medium follows a second order rate law with negative fractional dependence on [OH-]. The active species are CrO and SbO+ and the negative dependence on [OH-] is due to the formation of SbO+ from antimony hydroxide species. The effect of ionic strength, solvent polarity, added complexing agent and ions is also studied. Activation parameters have also been evaluated. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights | CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.32A(12) [December 1993] | en_US |
| dc.title | Chromium(VI) oxidation of antimony(III) in an aqueous alkaline medium | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.32A(12) [December 1993] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 32A(12) 1095-1098.pdf | 252.21 kB | Adobe PDF | View/Open |
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and SbO+ and the negative dependence on [OH-] is due to the formation of SbO+ from antimony hydroxide species. The effect of ionic strength, solvent polarity, added complexing agent and ions is also studied. Activation parameters have also been evaluated.