Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/44075| Title: | Kinetics and mechanism of oxidation of nitrilotriacetate by poly(pyrldyl)iron(III) complexes and dodecatungstocobaltate(III) ion - A comparative study |
| Authors: | Ayoko, G Adefikayo Guinea, Papua New lyun, J Femii Mamman, Saratu |
| Issue Date: | Dec-1993 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Kinetics of oxidation of nitrilotriacetate by Fe(LL) ( -phenanthroline or bipyridine) and CoW12O have been investigated in aqueous acidic media. The reaction is first order each in reductant and oxidants but inversely proportional to acid concentration. The reactions are analysed by means of Schuster treatment of outer-sphere electron-transfer. |
| Page(s): | 1089-1091 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.32A(12) [December 1993] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 32A(12) 1089-1091.pdf | 192.19 kB | Adobe PDF | View/Open |
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(
-phenanthroline or bipyridine) and CoW12O
have been investigated in aqueous acidic media. The reaction is first order each in reductant and oxidants but inversely proportional to acid concentration. The reactions are analysed by means of Schuster treatment of outer-sphere electron-transfer.