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http://nopr.niscpr.res.in/handle/123456789/44082Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Saxena, Rashmi | - |
| dc.contributor.author | Upadhyay, S K | - |
| dc.date.accessioned | 2018-03-26T08:42:27Z | - |
| dc.date.available | 2018-03-26T08:42:27Z | - |
| dc.date.issued | 1993-12 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://nopr.niscair.res.in/handle/123456789/44082 | - |
| dc.description | 1060-1063 | en_US |
| dc.description.abstract | The kinetics of oxidation of palladium(II) catalysed oxidation of some hydroxyacids, viz, malic, citric and tartaric acids by N- bromosuccinimide have been studied in perchloric acid medium in the presence of mercuric acetate. A first order dependence of rate each in [oxidant] and [catalyst] has been observed. The order of reaction in substrate decreases at higher [substrate]. A retarding effect of [H+] on the rate has also been observed. A suitable mechanism consistent with observed kinetic data is proposed and discussed. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.32A(12) [December 1993] | en_US |
| dc.title | Kinetics and mechanism of palladium(II) catalysed oxidation of some hydroxyacids by N-bromosuccinimide in perchloric acid medium | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.32A(12) [December 1993] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 32A(12) 1060-1063.pdf | 285.24 kB | Adobe PDF | View/Open |
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