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http://nopr.niscpr.res.in/handle/123456789/44083| Title: | Kinetics and mechanism of oxidation of dimethylformamide (DMF) by diperiodato-nickelate(IV) (DPN) in aqueous alkaline medium |
| Authors: | Hugar, G H Nandibewoor, S T |
| Issue Date: | Dec-1993 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The title reaction is first order in [diperiodatonickelate(IV)] (DPN) and fractional order both in [dimethylformamide] (DMF) and [OH-]. Periodate has a retarding effect on the reaction. Effects of added products, ionic strength, dielectric constant of the reaction medium and temperature on the reaction have been examined. A mechanism has been proposed with MPN [monoperiodatonickel-ate(IV)] as the active oxidant. |
| Page(s): | 1056-1059 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.32A(12) [December 1993] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 32A(12) 1056-1059.pdf | 240.21 kB | Adobe PDF | View/Open |
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