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http://nopr.niscpr.res.in/handle/123456789/44084Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Selvaraj, Kappuswamy | - |
| dc.contributor.author | Hepsibha, E Mary | - |
| dc.contributor.author | Ratarajan, Krishnasamy | - |
| dc.contributor.author | Chandrasekara, Nallappan | - |
| dc.date.accessioned | 2018-03-26T08:52:00Z | - |
| dc.date.available | 2018-03-26T08:52:00Z | - |
| dc.date.issued | 1993-12 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://nopr.niscair.res.in/handle/123456789/44084 | - |
| dc.description | 1052-1055 | en_US |
| dc.description.abstract | Kinetics of oxidation of variously substituted epimeric pairs of 4-aminooxanes by chromium(VI) have been investigated in aqueous acetic acid in the presence of sulphuric acid. The results indicate that the oxidation is first order in [chromium(VI)] and fractional order in [aminooxane]. The reaction is acid catalysed and susceptible to solvent polarity. A mechanism involving the formation of an intermediate followed by abstraction of hydrogen in the rate limiting step is proposed. The reactivity of amino oxanes has been discussed n the basis of conformational and electronic effects. Activation parameters have also been determined. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.32A(12) [December 1993] | en_US |
| dc.title | Kinetics and mechanism of oxidation of 4-aminooxanes by chromium(IV) | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.32A(12) [December 1993] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 32A(12) 1052-1055.pdf | 281.29 kB | Adobe PDF | View/Open |
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