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http://nopr.niscpr.res.in/handle/123456789/45990| Title: | Reversible binding of carbon monoxide with Ru(III) aminopolycarboxylic acid complexes |
| Authors: | Khan, M M Taqui Khan, N H Kureshy, R I |
| Issue Date: | Nov-1992 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The reversible binding of carbon monoxide to the complexes [RuIII(EDTA-H)(H2O)] 1 and [RUIII(PDTA-H)(H2O)] 2 have been studied in aqueous solution at pH = 5 by spectrophotometric and electrochemical studies. The equilibrium constant for carbonylation, KCO was evaluated at 10°, 25° and 40°C. The thermodynamic parameters, DHᵒ, DGᵒ and DSᵒ for the carbonylation of the complexes 1 and 2 have been evaluated. The complex [Ru(PDTA-H)(CO)] 4 is more stable than the complex [Ru(EDTA-H)(CO)] 3 in solution. |
| Page(s): | 883-885 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.31A(11) [November 1992] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 31A(11) 883-885.pdf | 93.86 kB | Adobe PDF | View/Open |
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