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http://nopr.niscpr.res.in/handle/123456789/45996| Title: | Synthesis and spectroscopic studies of di-s-and t-butyltin(IV) carboxylates |
| Authors: | Jain, Vimal K Mokal, Vijaya B |
| Issue Date: | Nov-1992 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Di-s- and t-butyltin(IV) carboxylates, [Bu Sn(OOCAr)2] (x = sec. or tert.; Ar = C6H5, C6H4OMe-2,
2-C4H3O, 2-C4H3S, 2-C5H4N, 2-C9H6N and 2-C4H3N2) have been prepared and characterized. Carboxylate moiety acts in a bidentate fashion either by coordination through both the oxygen atoms in an
asymmetrical manner or chelating through nitrogen in case of ligands containing nitrogen heterocycles.
Spectroscopic data (IR and NMR) suggest that these compounds adopt a six-coordinate configuration in
solution. |
| Page(s): | 861-864 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.31A(11) [November 1992] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 31A(11) 861-864.pdf | 138.97 kB | Adobe PDF | View/Open |
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Sn(OOCAr)2] (x = sec. or tert.; Ar = C6H5, C6H4OMe-2,
2-C4H3O, 2-C4H3S, 2-C5H4N, 2-C9H6N and 2-C4H3N2) have been prepared and characterized. Carboxylate moiety acts in a bidentate fashion either by coordination through both the oxygen atoms in an
asymmetrical manner or chelating through nitrogen in case of ligands containing nitrogen heterocycles.
Spectroscopic data (IR and NMR) suggest that these compounds adopt a six-coordinate configuration in
solution.