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http://nopr.niscpr.res.in/handle/123456789/46011| Title: | Kinetics of oxidation of para- and meta-substituted benzaldehydes by pyridinium chlorochromate |
| Authors: | Pillay, M Krishna Jameel, A Abdul |
| Issue Date: | Jan-1992 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The oxidation of para- and meta-substituted ben-zaldehydes by pyridinium chlorochromate (PCC) is first order each in substrate, [PCC] and [H+J. Electron-releasing substituents retard and the electron-withdrawing groups enhance the rate. Addition of monomer to the reaction mixture gives a polymer. Activation parameters have been computed and a suitable mechanism has been postulated. |
| Page(s): | 46-48 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.31A(01) [January 1992] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJC 31A(1) 46-48.pdf | 2.13 MB | Adobe PDF | View/Open |
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