Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/46024
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dc.contributor.authorMandai, Subrata-
dc.contributor.authorMandaI, G C-
dc.contributor.authorShukla, R-
dc.contributor.authorBharadwaj, P K-
dc.date.accessioned2019-03-18T09:05:39Z-
dc.date.available2019-03-18T09:05:39Z-
dc.date.issued1992-02-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.identifier.urihttp://nopr.niscair.res.in/handle/123456789/46024-
dc.description128-130en_US
dc.description.abstractSulphur bridged dinuclear bismuth-molybdenum and bismuth-tungsten complexes are isolated when a DMSO solution of the bismuth complex (dtc) BiCl2 (dtc = diethyldithiocarbamate) is allowed to react with (NH4)2 MS4 (M =Mo, W). The two chloride ions are replaced by the tetrathiornetallato group which coordinates the bismuth moiety in a bidentate fashion forming two neutral complexes, (dtc)Bi(MS4)(M =Mo, W) in high yields (65-75%). The bidentate coordination of tetrathiometallates has been concluded on the basis of conductivity, infrared, elemental analysis and electronic and NMR spectral data.en_US
dc.language.isoen_USen_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.31A(02) [February 1992]en_US
dc.titleReactivity of bismuth(III) dichlorodithio-carbamate: Synthesis and spectroscopic characterisation of mixed bismuth-molybdenum and bismuth-tungsten complexesen_US
dc.typeArticleen_US
Appears in Collections:IJC-A Vol.31A(02) [February 1992]

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