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http://nopr.niscpr.res.in/handle/123456789/46052| Title: | Oxygen atom transfer reactions by Ru(V) oxo complexes: Models by cytochrome P450 oxidase |
| Authors: | Khan, M M Taqui Chatterjee, Debabrata Rao, A Prakash Mehta, S H |
| Issue Date: | Mar-1992 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Ruthenium(V) oxo complexes of the composition LRuv=O {L = ethylenediaminetetraacetate (ED-TA), propylenediaminetetraacetate (PDTA), N-hydroxyethylethylenediaminetriacetate (HEOTA)} and the ion [O = RuvCl2(H2O)3]+ act as excellent catalysts in the oxygen atom transfer reactions to organic substrates. These nonporphyrinic complexes of Ru(V) oxo species are isolated and are much more stable than the Fe(V) oxo complexes of the porphyrins. They are good models for the Cyt P-450 oxidase type of reactions. |
| Page(s): | 146-151 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.31A(03) [March 1992] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 31A(3) 146-151.pdf | 4.78 MB | Adobe PDF | View/Open |
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