Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/46182| Title: | Excited state proton transfer: An overview of environmental perturbations |
| Authors: | Chattopadhyay, Nitin Dutta, Rina chowdhary, Mihir |
| Issue Date: | Aug-1992 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Effect of environmental perturbations n the exicited state proton transfer (ESPT) reaction has been discussed. The perturbation is provided by the solvent or an external agent like crown ether, micelle-forming surfactant or cyclodextrin through changes in polarity and viscosity of the medium or some specific interaction with the probe. It has been observed that the perturbation has a marked effect on the equilibrium as well as on the kinetic rates of ESPT. For an encapsulated molecule the prototropic reaction has been shown to depend on the micro-environment as well as the molecular structure of the probe. |
| Page(s): | 512-517 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.31A(08) [August 1992] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 31A(8) 512-517.pdf | 510.15 kB | Adobe PDF | View/Open |
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