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http://nopr.niscpr.res.in/handle/123456789/46195| Title: | Influence of sodium lauryl sulfate micelles on the oxidation of malonic acid by chromic acid |
| Authors: | Panigrahi, G P Mishra, S K |
| Issue Date: | Sep-1992 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Malonic acid oxidation by Cr(VI) in the presence of sodium lauryl sulfate micelle is first order each in [Cr(VI)]and [H+] but second order in malonic acid. The oxidation is inhibited by NaLS. The observed reactions can be explained with the model proposed by Menger and Portnoy but does not fit to Berezin's model. The treatment leads to the conclusion that the reaction occurs in the aqueous phase and the active Cr(VI) species is H2CrO4. |
| Page(s): | 710-713 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.31A(09) [September 1992] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 31A(9) 710-713.pdf | 395.19 kB | Adobe PDF | View/Open |
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