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http://nopr.niscpr.res.in/handle/123456789/46198Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Ramalingam, S K | - |
| dc.contributor.author | Jeyasubramanian, K | - |
| dc.contributor.author | Abdulsamath, S | - |
| dc.date.accessioned | 2019-03-20T04:35:37Z | - |
| dc.date.available | 2019-03-20T04:35:37Z | - |
| dc.date.issued | 1992-09 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://nopr.niscair.res.in/handle/123456789/46198 | - |
| dc.description | 702-703 | en_US |
| dc.description.abstract | A direct iodination procedure is described for the introduction of iodine in the 3-position of the metal β-diketonates of Cr(III), Co(III), AI(III), Be(II), oxovanadium(IV), Ni(II) and Cu(II) employing monopyridine iodine(I) chloride in ethanol or methanol medium as a new iodinating reagent for β-diketonates. Unlike the reagents known already, monopyridineiodine(I) chloride gamma-iodinates at room temperature (in 10 min) giving 75-90% yield. On iodination, Ni(bzac)2 changes from the high spin to a low spin state due to steric factors. 3-Iodovandylacetylacetonate has been prepared for the first time using the present reagent. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.31A(09) [September 1992] | en_US |
| dc.title | Monopyridineiodine(I) chloride in ethanol as a new iodinating reagent for metal β-diketones and ketoneimines | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.31A(09) [September 1992] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 31A(9) 702-703.pdf | 258.39 kB | Adobe PDF | View/Open |
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