Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/46199
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dc.contributor.authorAhmed, I-
dc.contributor.authorAhmad, J U-
dc.contributor.authorKarim, M M-
dc.contributor.authorSarder, S I-
dc.contributor.authorUllah, S S-
dc.date.accessioned2019-03-20T04:37:35Z-
dc.date.available2019-03-20T04:37:35Z-
dc.date.issued1992-09-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.identifier.urihttp://nopr.niscair.res.in/handle/123456789/46199-
dc.description699-701en_US
dc.description.abstractThe metal carbonylate anion, Na[Fe(η5-C5H5)(CO)] reacts at room temperature with halogeno organic ligands 1,3,5-tris(bromomethyl)benzene and 1,2,4,5-tetrakis-(bromomethyl)benzene to give the complexes 1,3,5-tris- (σ-methylene) benzene {tris(η5-cyciopentadienyl)hexacarbonyliron} (1) and 1,2,4,5-tetrakis(σ-methylene) benzene {tetrakis(η5-cyclopentadienyl) octacarbonyliron} (3). The complex (1) undergoes thermal transformation to the corresponding π complex whereas, complex (3) does not due to the 18-electron rule formalism.en_US
dc.language.isoen_USen_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.31A(09) [September 1992]en_US
dc.titleσ-Bonded organometallics of iron and their facile conversion into π complexesen_US
dc.typeArticleen_US
Appears in Collections:IJC-A Vol.31A(09) [September 1992]

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